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By: siddude11 | Posted: Jun 27, 2012 | Physical Chemistry-1 | 1841 Views

Gaseous State Introduction


Matter can be classified into three categories depending upon its physical state namely solid, liquid and gaseous states. Solids have a definite volume and shape; liquids also have a definite volume but no definite shape; gases have neither a definite volume nor a definite shape.


MEASURABLE PROPERTIES OF GASES :


Mass, volume, temperature are the important measurable properties of gases.


Mass: The mass of the gas is related to the number of moles as


n = w/M


Where n = number of moles


w = mass of gas in grams


M = molecular mass of the gas


Volume: Since gases occupy the entire space available to them, therefore the gas volume means the volume of the container in which the gas is enclosed.


Units of Volume: Volume is generally expressed in litre or cm3 or dm3 1m3 = 103 litre


= 103 dm3 = 106 cm3.


Pressure: The force exerted by the gas per unit area on the walls of the container is equal to its pressure.


Units of Pressure: The pressure of a gas is expressed in atm, Pa, Nm–2, bar or, lb/In2 (psi).


760 mm = 1 atm = 10132.5 KP­a = 101325 Pa = 101325 Nm–2


760 mm of Hg = 1.01325 bar = 1013.25 milli bar = 14.7 lb/2n2 (psi)


Temperature: Temperature is defined as the degree of hotness. The SI unit of temperature is Kelvin. On the Celsius scale water freezes at 0°C and boils at 100°C where as in the Kelvin scale water freezes at 273 K and boils at 373 K.


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